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  Lewis acid activation of molybdenum nitrides for alkyne metathesis.

  Finke AD, Moore JS.

  Chem Commun (Camb). 2010 Nov 14;46(42):7939-41.

  The substantial kinetic barrier to molybdenum nitride-alkyne metathesis is facilitated by precomplexation of the borane Lewis acid B(C(6)F(5))(3), providing convenient access to metathesis-active molybdenum alkylidynes. Spectroscopic and X-ray structural analysis suggest Mo≡N bond weakening upon borane complexation.

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