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  Self-templating synthesis of hollow spheres of MOFs and their derived nanostructures.

  Chuan Tan Y, Chun Zeng H.

  Chem Commun (Camb). 2016 Oct 04;52(77):11591-4.

  An aqueous one-pot self-templating synthesis method to prepare highly uniform ZIF-67 hollow spheres (ZIF-67-HS) and their transition metal-doped derivatives (M/ZIF-67-HS, M = Cu and/or Zn) was developed. Extension of this approach to another important class of MOFs (metal carboxylates; e.g., HKUST-1) and facile design of derived nanostructures with complex architectures were also achieved.

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