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  Polymer@MOF@MOF: "grafting from" atom transfer radical polymerization for the synthesis of hybrid porous solids.

  McDonald KA, Feldblyum JI, Koh K, Wong-Foy AG, Matzger AJ.

  Chem Commun (Camb). 2015 Aug 04;51(60):11994-6.

  The application of a core-shell architecture allows the formation of a polymer-coated metal-organic framework (MOF) maintaining high surface area (2289-2857 m(2) g(-1)). The growth of a MOF shell from a MOF core was used to spatially localize initiators by post-synthetic modification. The confinement of initiators ensures that polymerization is restricted to the outer shell of the MOF.

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